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Ultrahigh oxygen-scavenging norbornene copolymers bearing imidazolyl iron complexes for fabricating active and sustainable packaging films.

Authors :
Wang Y
Hasegawa Y
Serikawa T
Oyaizu K
Nishide H
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2020 Jan 18; Vol. 56 (6), pp. 964-967. Date of Electronic Publication: 2019 Dec 20.
Publication Year :
2020

Abstract

A tough and transparent norbornene copolymer film affixing an imidazolyl iron-salen complex catalyst exhibited an ultra-high, humidity-independent, and monthly paced oxygen-scavenging capacity up to 300 mL (oxygen gas at STP)/g(film). The homogeneously dispersed and immobilized iron complex in the polymer matrix catalytically contributed to the exceptionally high-yield oxidative consumption of polymer allylic bonds.

Details

Language :
English
ISSN :
1364-548X
Volume :
56
Issue :
6
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
31859299
Full Text :
https://doi.org/10.1039/c9cc08788e