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Mechanochemical Palladium-Catalyzed Carbonylative Reactions Using Mo(CO) 6 .
- Source :
-
Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2020 Feb 26; Vol. 26 (12), pp. 2576-2580. Date of Electronic Publication: 2020 Feb 11. - Publication Year :
- 2020
-
Abstract
- Esters and amides were mechanochemically prepared by palladium-catalyzed carbonylative reactions of aryl iodides by using molybdenum hexacarbonyl as a convenient solid carbonyl source and avoiding a direct handling of gaseous carbon monoxide. Real-time monitoring of the mechanochemical reaction by in situ pressure sensing revealed that CO is rapidly transferred from Mo(CO) <subscript>6</subscript> to the active catalytic system without significant release of molecular carbon monoxide.<br /> (© 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.)
Details
- Language :
- English
- ISSN :
- 1521-3765
- Volume :
- 26
- Issue :
- 12
- Database :
- MEDLINE
- Journal :
- Chemistry (Weinheim an der Bergstrasse, Germany)
- Publication Type :
- Academic Journal
- Accession number :
- 31802549
- Full Text :
- https://doi.org/10.1002/chem.201904528