Facile Synthesis of Methylammonium Lead Iodide Perovskite with Controllable Morphologies with Enhanced Luminescence Performance.

Organic-inorganic hybrid perovskites with well-defined morphology have attracted much attention due to their unique photophysical properties. However, controlling the morphology of nanocrystalline perovskite to improve its photoelectric application remains a challenge. In this article, using a modified solution deposition method, we successfully synthesized uniform methylammonium lead iodide (MAPbI ₃ ) nanoplates, nanocubes, and nanorods and investigated the effect of morphology on the photoelectric properties of these materials. We found that the morphology can be controlled by regulating the amounts of reactant methylammonium iodide (MAI) and the rate at which MAPbI ₃ precursor is added into toluene solution, and that the corresponding size distributions can be optimized by tuning the final vacuum-drying temperature. The morphology has an obvious effect on the bandgap optimization and fluorescence enhancement of MAPbI ₃ , and the nanoplates exhibit stronger photoluminescence intensity and have a longer carrier lifetime than nanocubes and nanorods. The results show that the morphologies of MAPbI ₃ perovskite nanocrystals can be controlled by tuning the synthesizing conditions, and the MAPbI ₃ perovskite nanocrystals with special morphology can be used in special nanosize optoelectronic devices.
Competing Interests: The authors declare no conflicts of interest.