The first structural characterization of the proton-ated aza-cyclam ligand in catena -poly[[[(perchlorato)copper(II)]-μ-3-(3-carb-oxy-prop-yl)-1,5,8,12-tetra-aza-3-azonia-cyclo-tetra-deca-ne] bis-(per-chlorate)].

The asymmetric unit of the title com-pound, catena -poly[[[(perchlorato-κ O )copper(II)]-μ-3-(3-carb-oxy-prop-yl)-1,5,8,12-tetra-aza-3-azonia-cyclo-tetra-decane-κ ⁴ N ¹ , N ⁵ , N ⁸ , N ¹² ] bis-(per-chlorate)], {[Cu(C ₁₃ H ₃₀ N ₅ O ₂ )(ClO ₄ )](ClO ₄ ) ₂ } _n , (I), consists of a macrocyclic cation, one coordinated per-chlorate anion and two per-chlorate ions as counter-anions. The metal ion is coordinated in a tetra-gonally distorted octa-hedral geometry by the four secondary N atoms of the macrocyclic ligand, the mutually trans O atoms of the per-chlorate anion and the carbonyl O atom of the protonated carb-oxy-lic acid group of a neighbouring cation. The average equatorial Cu-N bond lengths [2.01 (6) Å] are significantly shorter than the axial Cu-O bond lengths [2.379 (8) Å for carboxyl-ate and average 2.62 (7) Å for disordered per-chlorate]. The coordinated macrocyclic ligand in (I) adopts the most energetically favourable trans -III conformation with an equatorial orientation of the substituent at the protonated distal 3-position N atom in a six-membered chelate ring. The coordination of the carb-oxy-lic acid group of the cation to a neighbouring com-plex unit results in the formation of infinite chains running along the b -axis direction, which are cross-linked by N-H⋯O hydrogen bonds between the secondary amine groups of the macrocycle and O atoms of the per-chlorate counter-anions to form sheets lying parallel to the (001) plane. Additionally, the extended structure of (I) is consolidated by numerous intra- and interchain C-H⋯O contacts.
(© Tsymbal et al. 2019.)