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Zn- and Cd-based Coordination Polymers Offering H-Bonding Cavities: Highly Selective Sensing of S 2 O 7 2- and Fe 3+ Ions.

Authors :
Kumar G
Pachisia S
Kumar P
Kumar V
Gupta R
Source :
Chemistry, an Asian journal [Chem Asian J] 2019 Dec 13; Vol. 14 (24), pp. 4594-4600. Date of Electronic Publication: 2019 Oct 29.
Publication Year :
2019

Abstract

We present two Zn <superscript>II</superscript> - and Cd <superscript>II</superscript> -based coordination polymers (CPs), L-Zn and L-Cd, offering H-bonding-based cavities of varying dimensions. Both CPs were used for the highly selective detection of S <subscript>2</subscript> O <subscript>7</subscript> <superscript>2-</superscript> and Fe <superscript>3+</superscript> ions where H-bonding based cavities played an important role. Fluorescence quenching, competitive binding studies and binding parameters substantiated significant recognition of S <subscript>2</subscript> O <subscript>7</subscript> <superscript>2-</superscript> and Fe <superscript>3+</superscript> ions by both CPs.<br /> (© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.)

Details

Language :
English
ISSN :
1861-471X
Volume :
14
Issue :
24
Database :
MEDLINE
Journal :
Chemistry, an Asian journal
Publication Type :
Academic Journal
Accession number :
31661197
Full Text :
https://doi.org/10.1002/asia.201901142