Amorphous Ionic Polymers with Color-Tunable Ultralong Organic Phosphorescence.

Authors :: Wang H
Shi H
Ye W
Yao X
Wang Q
Dong C
Jia W
Ma H
Cai S
Huang K
Fu L
Zhang Y
Zhi J
Gu L
Zhao Y
An Z
Huang W
Source :: Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2019 Dec 19; Vol. 58 (52), pp. 18776-18782. Date of Electronic Publication: 2019 Nov 27.
Publication Year :: 2019
Abstract: Amorphous purely organic phosphorescence materials with long-lived and color-tunable emission are rare. Herein, we report a concise chemical ionization strategy to endow conventional poly(4-vinylpyridine) (PVP) derivatives with ultralong organic phosphorescence (UOP) under ambient conditions. After the ionization of 1,4-butanesultone, the resulting PVP-S phosphor showed a UOP lifetime of 578.36 ms, which is 525 times longer than that of PVP polymer itself. Remarkably, multicolor UOP emission ranging from blue to red was observed with variation of the excitation wavelength, which has rarely been reported for organic luminescent materials. This finding not only provides a guideline for developing amorphous polymers with UOP properties, but also extends the scope of room-temperature phosphorescence (RTP) materials for practical applications in photoelectric fields.<br /> (© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.)