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Exploring the promising potential of MoS 2 -RuS 2 binary metal sulphide towards the electrocatalysis of antibiotic drug sulphadiazine.

Authors :
Sakthivel R
Kubendhiran S
Chen SM
Chen TW
Al-Zaqri N
Alsalme A
Alharthi FA
Abu Khanjer MM
Tseng TW
Huang CC
Source :
Analytica chimica acta [Anal Chim Acta] 2019 Dec 04; Vol. 1086, pp. 55-65. Date of Electronic Publication: 2019 Aug 06.
Publication Year :
2019

Abstract

Benefiting from the rich redox chemistry, high electrical conductivity and synergistic effect from two metal ions, the binary metal sulphides received tremendous attention in various applications. As a result, the MoS <subscript>2</subscript> -RuS <subscript>2</subscript> nanomaterial was synthesized through the simple one-pot hydrothermal technique. The electrocatalytic activity of the as-synthesized nanomaterial was exploited towards the electrochemical detection of antibiotic drug sulphadiazine (SDZ). The electrocatalytic oxidation of the SDZ exhibited lowest anodic peak potential and ehanced anodic peak current rather than other modified electrodes. Notably, an excellent electrochemical performance with very lowest limit of detection (LOD) of 0.004 μM, appreciable linear range from 0.01 μM to 598.7 μM and high sensitivity (2.333 μA μM <superscript>-1</superscript>  cm <superscript>-2</superscript> ) was obtained at MoS <subscript>2</subscript> -RuS <subscript>2</subscript> modified electrode. Moreover, well anti-interfering property, good operational stability, repeatability and reproducibility was achieved. Facinatingly, the practicability of the modified electrode demonstrated in milk and human serum samples.<br /> (Copyright © 2019 Elsevier B.V. All rights reserved.)

Details

Language :
English
ISSN :
1873-4324
Volume :
1086
Database :
MEDLINE
Journal :
Analytica chimica acta
Publication Type :
Academic Journal
Accession number :
31561794
Full Text :
https://doi.org/10.1016/j.aca.2019.07.073