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Rhodium-Catalyzed C-H Activation Enabled by an Indium Metalloligand.
- Source :
-
Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2019 Nov 25; Vol. 58 (48), pp. 17251-17254. Date of Electronic Publication: 2019 Oct 23. - Publication Year :
- 2019
-
Abstract
- Rhodium complexes with an indium metalloligand were successfully synthesized by utilizing a pyridine-tethered cyclopentadienyl ligand as a support for an In-Rh bond. The indium metalloligand dramatically changes the electronic and redox properties of the rhodium metal, thereby enabling catalysis of sp <superscript>2</superscript> C-H bond activation.<br /> (© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Details
- Language :
- English
- ISSN :
- 1521-3773
- Volume :
- 58
- Issue :
- 48
- Database :
- MEDLINE
- Journal :
- Angewandte Chemie (International ed. in English)
- Publication Type :
- Academic Journal
- Accession number :
- 31559666
- Full Text :
- https://doi.org/10.1002/anie.201910197