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Spin-crossover iron(ii) complex showing thermal hysteresis around room temperature with symmetry breaking and an unusually high T(LIESST) of 120 K.

Authors :
García-López V
Palacios-Corella M
Cardona-Serra S
Clemente-León M
Coronado E
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2019 Oct 08; Vol. 55 (81), pp. 12227-12230.
Publication Year :
2019

Abstract

We report a Fe(ii) complex based on 4',4'' carboxylic acid disubstituted dipyrazolylpyridine that shows a spin-crossover close to room temperature associated to a crystallographic phase transition and the LIESST effect with a high T(LIESST) of 120 K.

Details

Language :
English
ISSN :
1364-548X
Volume :
55
Issue :
81
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
31552999
Full Text :
https://doi.org/10.1039/c9cc05988a