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Copper-catalyzed radical approach to allenyl iodides.

Authors :
Song Y
Song S
Duan X
Wu X
Jiang F
Zhang Y
Fan J
Huang X
Fu C
Ma S
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2019 Sep 26; Vol. 55 (78), pp. 11774-11777.
Publication Year :
2019

Abstract

A copper-catalyzed 1,4-addition reaction of sulfonyl iodides with 1,3-enynes affording various allenyl halides in high yields under mild conditions has been developed. Mechanistic studies showed that the reaction proceeds through a radical mechanism.

Details

Language :
English
ISSN :
1364-548X
Volume :
55
Issue :
78
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
31515552
Full Text :
https://doi.org/10.1039/c9cc05853b