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A safe and sustainable bacterial cellulose nanofiber separator for lithium rechargeable batteries.

Authors :
Gwon H
Park K
Chung SC
Kim RH
Kang JK
Ji SM
Kim NJ
Lee S
Ku JH
Do EC
Park S
Kim M
Shim WY
Rhee HS
Kim JY
Kim J
Kim TY
Yamaguchi Y
Iwamuro R
Saito S
Kim G
Jung IS
Park H
Lee C
Lee S
Jeon WS
Jang WD
Kim HU
Lee SY
Im D
Doo SG
Lee SY
Lee HC
Park JH
Source :
Proceedings of the National Academy of Sciences of the United States of America [Proc Natl Acad Sci U S A] 2019 Sep 24; Vol. 116 (39), pp. 19288-19293. Date of Electronic Publication: 2019 Sep 09.
Publication Year :
2019

Abstract

Bacterial cellulose nanofiber (BCNF) with high thermal stability produced by an ecofriendly process has emerged as a promising solution to realize safe and sustainable materials in the large-scale battery. However, an understanding of the actual thermal behavior of the BCNF in the full-cell battery has been lacking, and the yield is still limited for commercialization. Here, we report the entire process of BCNF production and battery manufacture. We systematically constructed a strain with the highest yield (31.5%) by increasing metabolic flux and improved safety by introducing a Lewis base to overcome thermochemical degradation in the battery. This report will open ways of exploiting the BCNF as a "single-layer" separator, a good alternative to the existing chemical-derived one, and thus can greatly contribute to solving the environmental and safety issues.<br />Competing Interests: The authors declare no conflict of interest.

Details

Language :
English
ISSN :
1091-6490
Volume :
116
Issue :
39
Database :
MEDLINE
Journal :
Proceedings of the National Academy of Sciences of the United States of America
Publication Type :
Academic Journal
Accession number :
31501346
Full Text :
https://doi.org/10.1073/pnas.1905527116