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Side-On Coordination of Nitrous Oxide to a Mononuclear Cobalt Center.
- Source :
-
Journal of the American Chemical Society [J Am Chem Soc] 2019 Sep 25; Vol. 141 (38), pp. 15003-15007. Date of Electronic Publication: 2019 Sep 11. - Publication Year :
- 2019
-
Abstract
- Despite its utility as an oxygen-atom transfer reagent for transition metals, nitrous oxide (N <subscript>2</subscript> O) is a notoriously poor ligand, and its coordination chemistry has been limited to a few terminal, end-on κ <superscript>1</superscript> - N complexes. Here, the synthesis of a mononuclear cobalt complex possessing a side-on-bound N <subscript>2</subscript> O molecule is reported. Structural characterization, IR spectroscopy, and DFT calculations support an η <superscript>2</superscript> - N,N binding mode for binding of N <subscript>2</subscript> O to the cobalt center.
Details
- Language :
- English
- ISSN :
- 1520-5126
- Volume :
- 141
- Issue :
- 38
- Database :
- MEDLINE
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 31492053
- Full Text :
- https://doi.org/10.1021/jacs.9b08241