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Synthesis and Reactivity of 5-Heterotruxenes Containing Sulfur or Nitrogen as the Heteroatom.
- Source :
-
The Journal of organic chemistry [J Org Chem] 2019 Sep 20; Vol. 84 (18), pp. 11553-11561. Date of Electronic Publication: 2019 Sep 11. - Publication Year :
- 2019
-
Abstract
- This paper presents an alternative path for the synthesis of 5-thiatruxene and the synthetic approach for 5-azatruxene not known so far. A new method for 5-thiatruxene improves the overall reaction yield from 17.5 to 22.6%, diminishes the synthesis time and costs by reducing synthetic steps from 5 to 2, and simplifies the isolation of intermediate and final products. The overall reaction yield for 5-azatruxene is 32.4%. The typical reactivity of both aromatic systems is also demonstrated. Recent research results suggest the use of 5-thiatruxene as the acceptor subunit of soluble blue emitters.
Details
- Language :
- English
- ISSN :
- 1520-6904
- Volume :
- 84
- Issue :
- 18
- Database :
- MEDLINE
- Journal :
- The Journal of organic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 31475531
- Full Text :
- https://doi.org/10.1021/acs.joc.9b01397