3D highly branched PtCoRh nanoassemblies: Glycine-assisted solvothermal synthesis and superior catalytic activity for alcohol oxidation.

Advanced Pt-based ternary nanocatalysts display dramatically enhanced utilization efficiency of Pt alternative to mono- and bi-counterparts, owing to the synergistic effects of the tri-metals. Herein, multicomponent uniform 3D PtCoRh highly branched nanoassemblies (HBNAs) were prepared by glycine-assisted one-pot solvothermal method in oleylamine (OAm). The effects of the precursor types, reaction time and amount of glycine were critically investigated in this synthesis. The as-prepared PtCoRh HBNAs displayed outstanding electrocatalytic activity and improved stability towards ethanol oxidation reaction (EOR) and methanol oxidation reaction (MOR) in 1 M KOH electrolyte, whose mass/specific activities were 1.75 A mg ^-1 /4.03 mA cm ^-2 and 0.98 A mg ^-1 /2.34 mA cm ^-2 , respectively, which were remarkably higher than commercial Pt/C (0.85 A mg ^-1 /4.03 mA cm ^-2 and 0.47 A mg ^-1 /0.89 mA cm ^-2 ). This study provides some novel guidelines to fabricate advanced multimetallic electrocatalysts for practical applications in direct alcohol fuel cells (DAFCs).
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