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Triplet dynamic nuclear polarization of nanocrystals dispersed in water at room temperature.

Authors :
Nishimura K
Kouno H
Tateishi K
Uesaka T
Ideta K
Kimizuka N
Yanai N
Source :
Physical chemistry chemical physics : PCCP [Phys Chem Chem Phys] 2019 Aug 14; Vol. 21 (30), pp. 16408-16412. Date of Electronic Publication: 2019 Jul 08.
Publication Year :
2019

Abstract

While dynamic nuclear polarization using photo-excited triplet electrons (triplet-DNP) can improve the sensitivity of nuclear magnetic resonance at room temperature, it has not been carried out in water. Here, we report the first example of triplet-DNP in water by downsizing the conventional bulk crystals to nanocrystals.

Details

Language :
English
ISSN :
1463-9084
Volume :
21
Issue :
30
Database :
MEDLINE
Journal :
Physical chemistry chemical physics : PCCP
Publication Type :
Academic Journal
Accession number :
31282507
Full Text :
https://doi.org/10.1039/c9cp03330k