Stable cyclic (alkyl)(amino)carbene (cAAC) radicals with main group substituents.

Isolation and characterization of stable radicals has been a long-pursued quest. While there has been some progress in this field particularly with respect to carbon, radicals involving heavier p-block elements are still considerably sparse. In this review we describe our recent successful efforts on the isolation of stable p-block element radicals particularly those involving aluminum, silicon, and phosphorus.