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Stabilized Gallylene in a Pincer-Type Ligand: Synthesis, Structure, and Reactivity of PGa I P-Ir Complexes.
- Source :
-
Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2019 Jul 15; Vol. 58 (29), pp. 9998-10002. Date of Electronic Publication: 2019 Jun 24. - Publication Year :
- 2019
-
Abstract
- Iridium complexes having a pincer-type gallylene ligand were successfully synthesized utilizing bis(phosphino)terpyridine as an efficient scaffold for the Ir-Ga <superscript>I</superscript> bond. The stabilization of the gallylene moiety by the pincer-type structure enabled various reactions at Ir with keeping the gallylene ligand intact, leading to unique structures and reactivities of PGa <superscript>I</superscript> P-Ir complexes.<br /> (© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Details
- Language :
- English
- ISSN :
- 1521-3773
- Volume :
- 58
- Issue :
- 29
- Database :
- MEDLINE
- Journal :
- Angewandte Chemie (International ed. in English)
- Publication Type :
- Academic Journal
- Accession number :
- 31081223
- Full Text :
- https://doi.org/10.1002/anie.201904968