Radiolysis of supercritical water at 400 °C: density dependence of the rate constant for the reaction of hydronium ions with hydrated electrons.

The rate constant, k(eaq- + H3O+), for the reaction of hydronium ions with hydrated electrons in supercritical water (SCW) at 400 °C has been evaluated as a function of water density using Monte Carlo track chemistry simulations of the radiolysis of SCW over the range of 0.15-0.6 g cm-3. Results are consistent with recent predictions using the so-called "cage effect" model.