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Sunlight-Induced Topochemical Photodimerization and Switching of the Conductivity of a Metal-Organic Compound.
- Source :
-
Inorganic chemistry [Inorg Chem] 2019 May 06; Vol. 58 (9), pp. 5419-5422. Date of Electronic Publication: 2019 Apr 12. - Publication Year :
- 2019
-
Abstract
- A metal-organic compound [Cd(quin) <subscript>2</subscript> (4-nvp) <subscript>2</subscript> ] [1; Hquin = quinoline-2-carboxylic acid and 4-nvp = 4-(1-naphthylvinyl)pyridine] undergoes topochemical [2 + 2] cycloaddition by sunlight irradiation to generate a one-dimensional coordination polymer. This reaction is thermally reversible, and switching between two crystalline forms can be monitored by conductivity measurements.
Details
- Language :
- English
- ISSN :
- 1520-510X
- Volume :
- 58
- Issue :
- 9
- Database :
- MEDLINE
- Journal :
- Inorganic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 30978011
- Full Text :
- https://doi.org/10.1021/acs.inorgchem.9b00619