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Tailoring the Porosity in Iron Phosphosulfide Nanosheets to Improve the Performance of Photocatalytic Hydrogen Evolution.
- Source :
-
ChemSusChem [ChemSusChem] 2019 Jun 21; Vol. 12 (12), pp. 2651-2659. Date of Electronic Publication: 2019 Jun 06. - Publication Year :
- 2019
-
Abstract
- Metal sulfide photocatalysts are typically required during water splitting to produce hydrogen. However, the rapid recombination of photogenerated electron-hole pairs in these highly unstable photocatalysts has restricted hydrogen production to small-scale batch reactions. In this work, porous transition-metal thiophosphites were used to enable continuous long-term hydrogen production through photocatalysis. A wide bandgap (2.04 eV) was essential for generating hydrogen at a rate of 305.6 μmol h <superscript>-1</superscript> g <superscript>-1</superscript> , 180 % faster than nonporous FePS <subscript>3</subscript> nanosheets. More importantly, the high in-plane stiffness of these approximately 7 nm thick porous FePS <subscript>3</subscript> nanosheets ensured structural stability during 56 h of continuous photocatalysis reactions. The reaction results with D <subscript>2</subscript> O instead of H <subscript>2</subscript> O indicated that hydrogen mainly came from H <subscript>2</subscript> O. Furthermore, a sacrificial reagent (triethylamine) was photodegraded into diethylamine and acetaldehyde through a monoelectronic oxidation process, as indicated by HPLC and LC-MS. This synthesis strategy reported for FePS <subscript>3</subscript> porous nanosheets paves a new pathway for designing other dianion-based inorganic nanocrystals for hydrogen energy applications.<br /> (© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Details
- Language :
- English
- ISSN :
- 1864-564X
- Volume :
- 12
- Issue :
- 12
- Database :
- MEDLINE
- Journal :
- ChemSusChem
- Publication Type :
- Academic Journal
- Accession number :
- 30972932
- Full Text :
- https://doi.org/10.1002/cssc.201900789