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Mn 2 CoReO 6 : a robust multisublattice antiferromagnetic perovskite with small A-site cations.

Authors :
Frank CE
McCabe EE
Orlandi F
Manuel P
Tan X
Deng Z
Croft M
Cascos V
Emge T
Feng HL
Lapidus S
Jin C
Wu M
Li MR
Ehrlich S
Khalid S
Quackenbush N
Yu S
Walker D
Greenblatt M
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2019 Mar 14; Vol. 55 (23), pp. 3331-3334.
Publication Year :
2019

Abstract

Mn2CoReO6, the fourth known magnetic transition-metal-only double perovskite oxide (space group P21/n) was synthesized at high pressure and temperature (8 GPa, 1350 °C). Large structural distortions are induced by the small A-site Mn2+ cations. Mn2CoReO6 exhibits complex magnetic properties with a robust antiferromagnetic order (TN = 94 K) involving all cation sublattices.

Details

Language :
English
ISSN :
1364-548X
Volume :
55
Issue :
23
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
30815646
Full Text :
https://doi.org/10.1039/c9cc00038k