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Facile and reversible double dearomatization of pyridines in non-phosphine Mn I complexes with N,S-donor pyridinophane ligand.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2019 Mar 18; Vol. 55 (22), pp. 3282-3285. Date of Electronic Publication: 2019 Feb 27. - Publication Year :
- 2019
-
Abstract
- Single and double dearomatization of pyridine rings was observed in Mn <superscript>I</superscript> complexes with an N2S2 pyridinophane ligand via deprotonation of one or two CH <subscript>2</subscript> arms, respectively. In contrast to other N,S-donor pincer-like systems, the dearomatized (N2S2)Mn species were found to be stable, with the dearomatization being reversible.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 55
- Issue :
- 22
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 30810134
- Full Text :
- https://doi.org/10.1039/c9cc00424f