Temporal evolution and pathway models of poly(ethylene-terephthalate) degradation under multi-factor accelerated weathering exposures.

Photolytic and hydrolytic degradation of poly(ethylene-terephthalate) (PET) polymers with different stabilizers were performed under multiple accelerated weathering exposures and changes in the polymers were monitored by various evaluation techniques. Yellowing was caused by photolytic degradation and haze formation was induced by combined effects of photolytic and hydrolytic degradation. The formation of light absorbing chromophores and bleaching of the UV stabilizer additive were recorded through optical spectroscopy. Chain scission and crystallization were found to be common mechanisms under both photolytic and hydrolytic conditions, based on the infrared absorption of the carbonyl (C = O) band and the trans ethylene glycol unit, respectively. The degradation mechanisms determined from these evaluations were then used to construct a set of degradation pathway network models using the network structural equation modeling (netSEM) approach. This method captured the temporal evolution of degradation by assessing statistically significant relationships between applied stressors, mechanistic variables, and performance level responses. Quantitative pathway equations provided the contributions from mechanistic variables to the response changes.
Competing Interests: The authors would like to acknowledge the support from 3M Corporate Research Laboratory (Agreement Control Number: 1401945). This does not alter our adherence to PLOS ONE policies on sharing data and materials. There are no patents, products in development, or marketed products to declare. The funder had no role in study design, data collection and analysis, interpretation of data, decision to publish, or preparation of the manuscript.