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Exceptional Adsorption and Binding of Sulfur Dioxide in a Robust Zirconium-Based Metal-Organic Framework.
- Source :
-
Journal of the American Chemical Society [J Am Chem Soc] 2018 Nov 21; Vol. 140 (46), pp. 15564-15567. Date of Electronic Publication: 2018 Nov 12. - Publication Year :
- 2018
-
Abstract
- We report a record-high SO <subscript>2</subscript> adsorption capacity of 12.3 mmol g <superscript>-1</superscript> in a robust porous material, MFM-601, at 298 K and 1.0 bar. SO <subscript>2</subscript> adsorption in MFM-601 is fully reversible and highly selective over CO <subscript>2</subscript> and N <subscript>2</subscript> . The binding domains for adsorbed SO <subscript>2</subscript> and CO <subscript>2</subscript> molecules in MFM-601 have been determined by in situ synchrotron X-ray diffraction experiments, giving insights at the molecular level to the basis of the observed high selectivity.
Details
- Language :
- English
- ISSN :
- 1520-5126
- Volume :
- 140
- Issue :
- 46
- Database :
- MEDLINE
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 30418751
- Full Text :
- https://doi.org/10.1021/jacs.8b08433