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Metal-Free Formal Inverse-Electron-Demand Diels-Alder Reaction of 1,2-Diazines with Ynamides.
- Source :
-
Organic letters [Org Lett] 2018 Oct 05; Vol. 20 (19), pp. 6055-6058. Date of Electronic Publication: 2018 Sep 20. - Publication Year :
- 2018
-
Abstract
- A highly effective metal-free formal inverse-electron-demand Diels-Alder reaction of 1,2-diazines with ynamides has been developed. This catalytic protocol is more environmentally friendly and allows for the construction of 2-aminonaphthalenes and 2-aminoanthracenes from 1,2-diazines and ynamides in good to high yields with wide diversity and functional group tolerance.
Details
- Language :
- English
- ISSN :
- 1523-7052
- Volume :
- 20
- Issue :
- 19
- Database :
- MEDLINE
- Journal :
- Organic letters
- Publication Type :
- Academic Journal
- Accession number :
- 30234310
- Full Text :
- https://doi.org/10.1021/acs.orglett.8b02431