Influence of advanced wood-fired appliances for residential heating on indoor air quality.

This work was aimed at studying particulate matter (PM) in the indoor atmosphere of two flats where airtight biomass systems were used for domestic heating. PM ₁₀ and PM _2.5 samples were collected by means of nine parallel sampling units, located in the outdoor and indoor areas of each flat. The samples were analyzed for PM macro-components (organic carbon, elemental carbon, macro-elements and inorganic ions) and for the soluble and residual fractions of micro-elements; the influence of the main PM sources on the indoor air quality was evaluated. The results confirm that infiltration from outdoor represents the main source of fine particles, while dust re-suspension, enhanced by the movements of the inhabitants, is one of the most important sources of coarse particles. Biomass-fueled heating systems are a significant source of indoor pollution, mainly due to the cleaning operations required for the removal of residual ash, which release particles in both the fine and the coarse size range. The impact of these operations resulted in indoor to outdoor ratios higher than one for most of the considered PM components. Very high amounts of copper and manganese, elements likely involved in the generation of oxidative stress, were released into the environment during ash removal from the pellet stove. Although this operation was very limited in time (about 15 min), the average concentration of Cu and Mn in PM ₁₀ and PM _2.5 during the study period (18 days) was more than six times (Cu) and about twice (Mn) the concentration values measured outdoors.
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