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(Deep) blue through-space conjugated TADF emitters based on [2.2]paracyclophanes.

(Deep) blue through-space conjugated TADF emitters based on [2.2]paracyclophanes.

Authors :
Spuling E
Sharma N
Samuel IDW
Zysman-Colman E
Bräse S
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2018 Aug 16; Vol. 54 (67), pp. 9278-9281.
Publication Year :
2018

Abstract

The first examples of through-space conjugated thermally activated delayed fluorescence (TADF) emitters based on a [2.2]paracyclophane (PCP) skeleton with stacked (coplanar) donor-acceptor groups have been synthesized. The optoelectronic properties are studied by the relative configuration, cis (pseudo-geminal) and trans (pseudo-para), of the donor and acceptor groups.

Details

Language :
English
ISSN :
1364-548X
Volume :
54
Issue :
67
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
30047551
Full Text :
https://doi.org/10.1039/c8cc04594a