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Design of Selective sPLA 2 -X Inhibitor (-)-2-{2-[Carbamoyl-6-(trifluoromethoxy)-1 H -indol-1-yl]pyridine-2-yl}propanoic Acid.

Authors :
Giordanetto F
Knerr L
Nordberg P
Pettersen D
Selmi N
Beisel HG
de la Motte H
Månsson Å
Dahlström M
Broddefalk J
Saarinen G
Klingegård F
Hurt-Camejo E
Rosengren B
Wikström J
Wågberg M
Brengdahl J
Rohman M
Sandmark J
Åkerud T
Roth RG
Jansen F
Ahlqvist M
Source :
ACS medicinal chemistry letters [ACS Med Chem Lett] 2018 Jun 23; Vol. 9 (7), pp. 600-605. Date of Electronic Publication: 2018 Jun 23 (Print Publication: 2018).
Publication Year :
2018

Abstract

A lead generation campaign identified indole-based sPLA <subscript>2</subscript> -X inhibitors with a promising selectivity profile against other sPLA <subscript>2</subscript> isoforms. Further optimization of sPLA <subscript>2</subscript> selectivity and metabolic stability resulted in the design of (-)- 17 , a novel, potent, and selective sPLA <subscript>2</subscript> -X inhibitor with an exquisite pharmacokinetic profile characterized by high absorption and low clearance, and low toxicological risk. Compound (-)- 17 was tested in an ApoE <superscript>-/-</superscript> murine model of atherosclerosis to evaluate the effect of reversible, pharmacological sPLA <subscript>2</subscript> -X inhibition on atherosclerosis development. Despite being well tolerated and achieving adequate systemic exposure of mechanistic relevance, (-)- 17 did not significantly affect circulating lipid and lipoprotein biomarkers and had no effect on coronary function or histological markers of atherosclerosis.<br />Competing Interests: The authors declare no competing financial interest.

Details

Language :
English
ISSN :
1948-5875
Volume :
9
Issue :
7
Database :
MEDLINE
Journal :
ACS medicinal chemistry letters
Publication Type :
Academic Journal
Accession number :
30034586
Full Text :
https://doi.org/10.1021/acsmedchemlett.7b00507