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Crystal structure and Hirshfeld surface analysis and energy frameworks of 1-(2,4-di-methyl-phen-yl)-4-(4-meth-oxy-phen-yl)naphthalene.

Authors :
Mohamooda Sumaya U
KarunaKaran J
Biruntha K
MohanaKrishnan AK
Usha G
Source :
Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2018 Jun 08; Vol. 74 (Pt 7), pp. 939-943. Date of Electronic Publication: 2018 Jun 08 (Print Publication: 2018).
Publication Year :
2018

Abstract

In the title compound, C <subscript>25</subscript> H <subscript>22</subscript> O, the two rings of the naphthalene system are inclined to each other by 3.06 (15)°. The mean plane of the naphthalene ring system makes a dihedral angle of 65.24 (12)° with the di-methyl-phenyl ring and 55.82 (12)° with the meth-oxy-phenyl ring. The di-methyl-phenyl ring is inclined to the meth-oxy-phenyl ring by 59.28 (14)°. In the crystal, adjacent mol-ecules are linked via C-H⋯π inter-actions, forming chains along [100]. Using Hirshfeld surface and two-dimensional fingerprint plots, the presence of short inter-molecular inter-actions in the crystal structure were analysed. The inter-molecular inter-action energies were also calculated and their distribution over the crystal structure was visualized graphically using energy frameworks.

Details

Language :
English
ISSN :
2056-9890
Volume :
74
Issue :
Pt 7
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Crystallographic communications
Publication Type :
Academic Journal
Accession number :
30002890
Full Text :
https://doi.org/10.1107/S2056989018008332