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"Total Synthesis" Supramolecular Style: Design and Hydrogen-Bond-Directed Assembly of Ternary Supermolecules.
- Source :
-
Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2001 Sep 03; Vol. 40 (17), pp. 3240-3242. - Publication Year :
- 2001
-
Abstract
- Getting the right balance between intermolecular interactions is crucial for the synthesis of supermolecules in a preconceived manner. The three-component supermolecule in the ternary cocrystal of 3,5-dinitrobenzoic acid, isonicotinamide, and 4-(dimethylamino)benzoic acid (1:1:1) assembles through a "primary" (between the stronger acid and pyridine) and a "secondary" hydrogen-bonding interaction (between the weaker acid and amide).<br /> (© 2001 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.)
Details
- Language :
- English
- ISSN :
- 1521-3773
- Volume :
- 40
- Issue :
- 17
- Database :
- MEDLINE
- Journal :
- Angewandte Chemie (International ed. in English)
- Publication Type :
- Academic Journal
- Accession number :
- 29712056
- Full Text :
- https://doi.org/10.1002/1521-3773(20010903)40:17<3240::AID-ANIE3240>3.0.CO;2-X