Back to Search
Start Over
High-Yielding Rotaxane Synthesis with an Anion Template.
- Source :
-
Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 1999 Feb 01; Vol. 38 (3), pp. 383-386. - Publication Year :
- 1999
-
Abstract
- An electrophile caught like a mouse in a trap! An anionic stopper-wheel complex acts as a supramolecular nucleophile in an almost quantitative synthesis of a phenyl ether rotaxane. The electrophilic semiaxle has to thread through the macrocycle in order to contact the bulky phenolate group that is positioned on the other side, and probably tightly held in place by hydrogen bonds.<br /> (© 1999 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.)
Details
- Language :
- English
- ISSN :
- 1521-3773
- Volume :
- 38
- Issue :
- 3
- Database :
- MEDLINE
- Journal :
- Angewandte Chemie (International ed. in English)
- Publication Type :
- Academic Journal
- Accession number :
- 29711647
- Full Text :
- https://doi.org/10.1002/(SICI)1521-3773(19990201)38:3<383::AID-ANIE383>3.0.CO;2-H