Back to Search Start Over

Scalable Synthesis of Hydrido-Disiloxanes from Silanes: A One-Pot Preparation of 1,3-Diphenyldisiloxane from Phenylsilane.

Authors :
Buonomo JA
Eiden CG
Aldrich CC
Source :
Synthesis [Synthesis (Stuttg)] 2018 Jan; Vol. 50 (2), pp. 278-281. Date of Electronic Publication: 2017 Sep 26.
Publication Year :
2018

Abstract

A simple, one-pot, and high-yielding synthesis of 1,3-diphenyldisiloxane is presented. The preparation of similar symmetrical disiloxane materials is also accomplished with this same protocol. This mechano-chemical procedure is efficient and highly scalable, furnishing a convenient route to hydrido-disiloxanes from widely accessible commercially available silanes.

Details

Language :
English
ISSN :
0039-7881
Volume :
50
Issue :
2
Database :
MEDLINE
Journal :
Synthesis
Publication Type :
Academic Journal
Accession number :
29662252
Full Text :
https://doi.org/10.1055/s-0036-1588580