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Enantioselective palladium-catalyzed allylic alkylation reactions in the synthesis of Aspidosperma and structurally related monoterpene indole alkaloids.
- Source :
-
Natural product reports [Nat Prod Rep] 2018 Jun 20; Vol. 35 (6), pp. 559-574. - Publication Year :
- 2018
-
Abstract
- Covering: up to the end of 2017 Enantioselective Pd-catalyzed allylic alkylations of prochiral enolates represent a powerful tool for the construction of all-carbon quaternary stereocenters. This review describes the emergence of such reactions as strategic linchpins that enable efficient, stereocontrolled syntheses of Aspidosperma and related monoterpene indole alkaloids.
- Subjects :
- Alkylation
Catalysis
Heterocyclic Compounds, 4 or More Rings chemical synthesis
Heterocyclic Compounds, 4 or More Rings chemistry
Indole Alkaloids chemistry
Molecular Structure
Monoterpenes chemistry
Palladium
Stereoisomerism
Aspidosperma chemistry
Indole Alkaloids chemical synthesis
Monoterpenes chemical synthesis
Subjects
Details
- Language :
- English
- ISSN :
- 1460-4752
- Volume :
- 35
- Issue :
- 6
- Database :
- MEDLINE
- Journal :
- Natural product reports
- Publication Type :
- Academic Journal
- Accession number :
- 29658039
- Full Text :
- https://doi.org/10.1039/c7np00069c