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Ruthenium-Catalyzed Hydrogenation of Carbocyclic Aromatic Amines: Access to Chiral Exocyclic Amines.

Authors :
Yan Z
Xie HP
Shen HQ
Zhou YG
Source :
Organic letters [Org Lett] 2018 Feb 16; Vol. 20 (4), pp. 1094-1097. Date of Electronic Publication: 2018 Jan 30.
Publication Year :
2018

Abstract

The first highly enantioselective hydrogenation of carbocyclic aromatic amines has been successfully realized using in situ-generated chiral ruthenium complex as catalyst, affording facile access to chiral exocyclic amines with up to 98% ee.

Details

Language :
English
ISSN :
1523-7052
Volume :
20
Issue :
4
Database :
MEDLINE
Journal :
Organic letters
Publication Type :
Academic Journal
Accession number :
29380604
Full Text :
https://doi.org/10.1021/acs.orglett.7b04060