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Phosphinoyl Radical-Initiated 1,2-Bifunctional Thiocyanodiphenylphosphinoylation of Alkenes.

Authors :
Tao ZK
Li CK
Zhang PZ
Shoberu A
Zou JP
Zhang W
Source :
The Journal of organic chemistry [J Org Chem] 2018 Feb 16; Vol. 83 (4), pp. 2418-2424. Date of Electronic Publication: 2018 Feb 05.
Publication Year :
2018

Abstract

1,2-Bifuctional thiocyanodiphenylphosphinoylation of alkenes is established through the phosphinoyl radical addition followed by Cu-catalyzed thiocyanation. This one-pot reaction is applicable to a range of aromatic, aliphatic, and cyclic alkenes to afford thiocyanodiphenylphosphinoylated compounds in satisfactory yields.

Details

Language :
English
ISSN :
1520-6904
Volume :
83
Issue :
4
Database :
MEDLINE
Journal :
The Journal of organic chemistry
Publication Type :
Academic Journal
Accession number :
29376357
Full Text :
https://doi.org/10.1021/acs.joc.7b02929