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Fingerprinting the Nature of Anions in Pyrylium Complexes: Dual Binding Mode for Anion-π Interactions.
- Source :
-
Chemphyschem : a European journal of chemical physics and physical chemistry [Chemphyschem] 2018 Feb 05; Vol. 19 (3), pp. 327-334. Date of Electronic Publication: 2018 Jan 05. - Publication Year :
- 2018
-
Abstract
- The interplay between noncovalent interactions that involve oxygenated heteroaromatic rings have been studied for the first time in this work. In particular, we report an advance in knowledge-based anion-π interactions together with (C-H) <superscript>+</superscript> ⋅⋅⋅anion contacts. To understand how the anion modulates these interactions, the synthesis of pyrylium salts with a variety of anions was performed by using an anionic metathesis methodology. The synthesized pyrylium complexes were classified in series, for example, anions derived from halogens, from oxoacids, from p-block elements, and from transition metals. Crystallographic data, DFT calculations, and NMR spectroscopy methods provided access to an overall insight into the noncovalent behavior of the anion in this kind of system. Based on the DFT calculations and <superscript>1</superscript> H NMR spectroscopy, pyrylium protons can be used as chemical tags to detect noncovalent interactions in this type of compound.<br /> (© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Details
- Language :
- English
- ISSN :
- 1439-7641
- Volume :
- 19
- Issue :
- 3
- Database :
- MEDLINE
- Journal :
- Chemphyschem : a European journal of chemical physics and physical chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 29215788
- Full Text :
- https://doi.org/10.1002/cphc.201700981