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Mononuclear Alkali Metal Organoperoxides Stabilized by an NNNN-Macrocycle and Short Hydrogen Bonds from ROOH Molecules.
- Source :
-
Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2017 Dec 06; Vol. 23 (68), pp. 17213-17216. Date of Electronic Publication: 2017 Nov 22. - Publication Year :
- 2017
-
Abstract
- A series of light alkali metal organoperoxides [MOOR] (M=Li, Na, K; R=tBu, CMe <subscript>2</subscript> Ph) were isolated in mononuclear form, aided by the tetradentate and neutral NNNN-type macrocycle Me <subscript>4</subscript> TACD (L; Me <subscript>4</subscript> [12]aneN <subscript>4</subscript> =1,4,7,10-tetramethyl-1,4,7,10-tetraazacyclododecane) and strong hydrogen bonds from additional ROOH molecules. The Na and K compounds are characterized by short O-Hâ‹…â‹…â‹…O contacts, in the case of the Na derivative as short as 2.41 Å.<br /> (© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Details
- Language :
- English
- ISSN :
- 1521-3765
- Volume :
- 23
- Issue :
- 68
- Database :
- MEDLINE
- Journal :
- Chemistry (Weinheim an der Bergstrasse, Germany)
- Publication Type :
- Academic Journal
- Accession number :
- 29083060
- Full Text :
- https://doi.org/10.1002/chem.201704758