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Communication: Master equations for electron transport: The limits of the Markovian limit.

Authors :
Elenewski JE
Gruss D
Zwolak M
Source :
The Journal of chemical physics [J Chem Phys] 2017 Oct 21; Vol. 147 (15), pp. 151101.
Publication Year :
2017

Abstract

Master equations are increasingly popular for the simulation of time-dependent electronic transport in nanoscale devices. Several recent Markovian approaches use "extended reservoirs"-explicit degrees of freedom associated with the electrodes-distinguishing them from many previous classes of master equations. Starting from a Lindblad equation, we develop a common foundation for these approaches. Due to the incorporation of explicit electrode states, these methods do not require a large bias or even "true Markovianity" of the reservoirs. Nonetheless, their predictions are only physically relevant when the Markovian relaxation is weaker than the thermal broadening and when the extended reservoirs are "sufficiently large," in a sense that we quantify. These considerations hold despite complete positivity and respect for Pauli exclusion at any relaxation strength.

Details

Language :
English
ISSN :
1089-7690
Volume :
147
Issue :
15
Database :
MEDLINE
Journal :
The Journal of chemical physics
Publication Type :
Academic Journal
Accession number :
29055298
Full Text :
https://doi.org/10.1063/1.5000747