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Phosphinoyl Radical Initiated Vicinal Cyanophosphinoylation of Alkenes.
- Source :
-
Organic letters [Org Lett] 2017 Oct 20; Vol. 19 (20), pp. 5537-5540. Date of Electronic Publication: 2017 Oct 02. - Publication Year :
- 2017
-
Abstract
- A double-functionalization reaction of alkenes through Mn(OAc) <subscript>3</subscript> -mediated phosphinoyl radical addition followed by CuCN-catalyzed cyanation is introduced. This one-pot reaction is performed under mild conditions to afford vicinal cyanophosphinoylation products.
Details
- Language :
- English
- ISSN :
- 1523-7052
- Volume :
- 19
- Issue :
- 20
- Database :
- MEDLINE
- Journal :
- Organic letters
- Publication Type :
- Academic Journal
- Accession number :
- 28968118
- Full Text :
- https://doi.org/10.1021/acs.orglett.7b02621