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Microwave-Assisted Rapid One-Pot Synthesis of Fused and Non-Fused Indoles and 5-[ 18 F]Fluoroindoles from Phenylazocarboxylates.

Authors :
Krüll J
Hubert A
Nebel N
Prante O
Heinrich MR
Source :
Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2017 Nov 16; Vol. 23 (64), pp. 16174-16178. Date of Electronic Publication: 2017 Oct 23.
Publication Year :
2017

Abstract

Substituted indoles can be prepared from phenylazocarboxylates through a rapid one-pot sequence featuring a microwave-assisted Fischer indole synthesis as a key step. Considering that the phenylazocarboxylates may beforehand be modified by mild nucleophilic aromatic substitution, including the introduction of [ <superscript>18</superscript> F]fluoride, the overall strategy offers an attractive new access to 5-[ <superscript>18</superscript> F]fluoroindoles.<br /> (© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.)

Details

Language :
English
ISSN :
1521-3765
Volume :
23
Issue :
64
Database :
MEDLINE
Journal :
Chemistry (Weinheim an der Bergstrasse, Germany)
Publication Type :
Academic Journal
Accession number :
28940808
Full Text :
https://doi.org/10.1002/chem.201703890