Crystal structure of N -(7-di-bromo-methyl-5-methyl-1,8-naphthyridin-2-yl)benzamide-pyrrolidine-2,5-dione (1/1).

Authors :: Wang BZ
Zhou JP
Zhou Y
Luo JS
Yang JJ
Chi SM
Source :: Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2017 Jan 01; Vol. 73 (Pt 1), pp. 1-3. Date of Electronic Publication: 2017 Jan 01 (Print Publication: 2017).
Publication Year :: 2017
Abstract: The title compound, C <subscript>17</subscript> H <subscript>13</subscript> Br <subscript>2</subscript> N <subscript>3</subscript> O·C <subscript>4</subscript> H <subscript>5</subscript> NO <subscript>2</subscript> , is a co-crystal of N -(7-di-bromo-methyl-5-methyl-1,8-naphthyridin-2-yl)benzamide and pyrrolidine-2,5-dione (succinimide). The benzamide mol-ecule exhibits pseudo-mirror symmetry, with an r.m.s. deviation of the non-H atoms of 0.09 Å (except for the two Br atoms). The angle between the least-squares planes of the two mol-ecules is 26.2 (2)°. In the crystal, the two mol-ecules are mutually linked by N-H⋯O and N-H⋯N hydrogen bonds. The packing is consolidated by C-H⋯(O,N) hydrogen bonds and π-π stacking inter-actions.

Language :: English
ISSN :: 2056-9890
Volume :: 73
Issue :: Pt 1
Database :: MEDLINE
Journal :: Acta crystallographica. Section E, Crystallographic communications
Publication Type :: Academic Journal
Accession number :: 28083121
Full Text :: https://doi.org/10.1107/S2056989016019034

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