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Gallium-Doped Li 7 La 3 Zr 2 O 12 Garnet-Type Electrolytes with High Lithium-Ion Conductivity.
- Source :
-
ACS applied materials & interfaces [ACS Appl Mater Interfaces] 2017 Jan 18; Vol. 9 (2), pp. 1542-1552. Date of Electronic Publication: 2017 Jan 05. - Publication Year :
- 2017
-
Abstract
- Owing to their high conductivity, crystalline Li <subscript>7-3x</subscript> Ga <subscript>x</subscript> La <subscript>3</subscript> Zr <subscript>2</subscript> O <subscript>12</subscript> garnets are promising electrolytes for all-solid-state lithium-ion batteries. Herein, the influence of Ga doping on the phase, lithium-ion distribution, and conductivity of Li <subscript>7-3x</subscript> Ga <subscript>x</subscript> La <subscript>3</subscript> Zr <subscript>2</subscript> O <subscript>12</subscript> garnets is investigated, with the determined concentration and mobility of lithium ions shedding light on the origin of the high conductivity of Li <subscript>7-3x</subscript> Ga <subscript>x</subscript> La <subscript>3</subscript> Zr <subscript>2</subscript> O <subscript>12</subscript> . When the Ga concentration exceeds 0.20 Ga per formula unit, the garnet-type material is found to assume a cubic structure, but lower Ga concentrations result in the coexistence of cubic and tetragonal phases. Most lithium within Li <subscript>7-3x</subscript> Ga <subscript>x</subscript> La <subscript>3</subscript> Zr <subscript>2</subscript> O <subscript>12</subscript> is found to reside at the octahedral 96h site, away from the central octahedral 48g site, while the remaining lithium resides at the tetrahedral 24d site. Such kind of lithium distribution leads to high lithium-ion mobility, which is the origin of the high conductivity; the highest lithium-ion conductivity of 1.46 mS/cm at 25 °C is found to be achieved for Li <subscript>7-3x</subscript> Ga <subscript>x</subscript> La <subscript>3</subscript> Zr <subscript>2</subscript> O <subscript>12</subscript> at x = 0.25. Additionally, there are two lithium-ion migration pathways in the Li <subscript>7-3x</subscript> Ga <subscript>x</subscript> La <subscript>3</subscript> Zr <subscript>2</subscript> O <subscript>12</subscript> garnets: 96h-96h and 24d-96h-24d, but the lithium ions transporting through the 96h-96h pathway determine the overall conductivity.
Details
- Language :
- English
- ISSN :
- 1944-8252
- Volume :
- 9
- Issue :
- 2
- Database :
- MEDLINE
- Journal :
- ACS applied materials & interfaces
- Publication Type :
- Academic Journal
- Accession number :
- 28004907
- Full Text :
- https://doi.org/10.1021/acsami.6b13902