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Efficient Synthetic Routes to (±)-Hippolachnin A, (±)-Gracilioethers E and F and the Alleged Structure of (±)-Gracilioether I.
- Source :
-
Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2017 Feb 10; Vol. 23 (9), pp. 2026-2030. Date of Electronic Publication: 2017 Jan 23. - Publication Year :
- 2017
-
Abstract
- Two monocyclic members in the gracilioether family were synthesized in only three steps. The monocyclic products were further elaborated into advanced precursors to hippolachnin A and gracilioether E, respectively. Gracilioether F and the alleged structure for gracilioether I were also synthesized using a late-stage C(sp <superscript>3</superscript> )-H thermo-oxidation.<br /> (© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.)
- Subjects :
- Cycloaddition Reaction
Ethers, Cyclic chemical synthesis
Heterocyclic Compounds, 3-Ring chemical synthesis
Molecular Conformation
Oxidation-Reduction
Polyketides chemical synthesis
Stereoisomerism
Temperature
Ethers, Cyclic chemistry
Heterocyclic Compounds, 3-Ring chemistry
Polyketides chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 1521-3765
- Volume :
- 23
- Issue :
- 9
- Database :
- MEDLINE
- Journal :
- Chemistry (Weinheim an der Bergstrasse, Germany)
- Publication Type :
- Academic Journal
- Accession number :
- 27957781
- Full Text :
- https://doi.org/10.1002/chem.201605776