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Pentafluoroethyl Bismuth Compounds.
- Source :
-
Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2017 Jan 31; Vol. 23 (7), pp. 1557-1567. Date of Electronic Publication: 2017 Jan 17. - Publication Year :
- 2017
-
Abstract
- A series of tris-, bis-, and mono(pentafluoroethyl)bismuthanes of the type (C <subscript>2</subscript> F <subscript>5</subscript> ) <subscript>n</subscript> BiX <subscript>3-n</subscript> (X=F, Cl, Br, I) and transition metal complexes are accessible by a sophisticated pentafluoroethylation protocol. Chemical properties, induced by the strongly electron-withdrawing character of C <subscript>2</subscript> F <subscript>5</subscript> groups, are described for representative examples. Moreover, the first molecular structures of perfluoroalkyl bismuthanes and bismuthates obtained by X-ray diffraction are presented.<br /> (© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Details
- Language :
- English
- ISSN :
- 1521-3765
- Volume :
- 23
- Issue :
- 7
- Database :
- MEDLINE
- Journal :
- Chemistry (Weinheim an der Bergstrasse, Germany)
- Publication Type :
- Academic Journal
- Accession number :
- 27862439
- Full Text :
- https://doi.org/10.1002/chem.201604910