Back to Search Start Over

Stereoelectronic Chameleons: The Donor-Acceptor Dichotomy of Functional Groups.

Authors :
Vatsadze SZ
Loginova YD
Dos Passos Gomes G
Alabugin IV
Source :
Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2017 Mar 08; Vol. 23 (14), pp. 3225-3245. Date of Electronic Publication: 2016 Nov 11.
Publication Year :
2017

Abstract

Stereoelectronic factors account for the apparent reversal of donor-acceptor properties of a variety of functional groups by a simple change of their orientation in space. The new reactivity patterns that arise from spatial anisotropy are associated with chameleonic behavior of common organic functionalities.<br /> (© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.)

Details

Language :
English
ISSN :
1521-3765
Volume :
23
Issue :
14
Database :
MEDLINE
Journal :
Chemistry (Weinheim an der Bergstrasse, Germany)
Publication Type :
Academic Journal
Accession number :
27862399
Full Text :
https://doi.org/10.1002/chem.201603491