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Crystal structure of 9-(di-bromo-meth-yl)-1,1-di-fluoro-3,7-dimethyl-1 H -[1,3,5,2]oxadi-aza-borinino[3,4- a ][1,8]naphthyridin-11-ium-1-uide.

Authors :
Wang BZ
Zhou JP
Zhou Y
Luo JS
Chi SM
Source :
Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2016 Oct 25; Vol. 72 (Pt 11), pp. 1642-1644. Date of Electronic Publication: 2016 Oct 25 (Print Publication: 2016).
Publication Year :
2016

Abstract

The mol-ecule of the title 1,8-naphthyridine-BF <subscript>2</subscript> derivative, C <subscript>12</subscript> H <subscript>10</subscript> BBr <subscript>2</subscript> F <subscript>2</subscript> N <subscript>3</subscript> O, is located on a mirror plane running parallel to the entire ring system and the attached methyl C atoms. Individual mol-ecules are stacked along the b- axis direction. The cohesion in the crystal structure is accomplished by C-H⋯F hydrogen bonds and additional off-set π-π inter-actions [centroid-to-centroid distance = 3.6392 (9) Å, slippage 0.472 Å], leading to the formation of a three-dimensional supra-molecular network.

Details

Language :
English
ISSN :
2056-9890
Volume :
72
Issue :
Pt 11
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Crystallographic communications
Publication Type :
Academic Journal
Accession number :
27840726
Full Text :
https://doi.org/10.1107/S2056989016016704