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N-Heterocyclic Carbene Catalyzed Sulfenylation of α,β-Unsaturated Aldehydes.

Authors :
Dong YT
Jin Q
Zhou L
Chen J
Source :
Organic letters [Org Lett] 2016 Nov 04; Vol. 18 (21), pp. 5708-5711. Date of Electronic Publication: 2016 Oct 27.
Publication Year :
2016

Abstract

An efficient N-heterocyclic carbene (NHC) catalyzed sulfenylation reaction of α,β-unsaturated aldehydes with N-(arylthio)phthalimide has been developed. A wide variety of α-thioenals can be obtained with good to excellent yields and excellent Z-configuration.

Details

Language :
English
ISSN :
1523-7052
Volume :
18
Issue :
21
Database :
MEDLINE
Journal :
Organic letters
Publication Type :
Academic Journal
Accession number :
27786491
Full Text :
https://doi.org/10.1021/acs.orglett.6b02939