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Rhodium-Catalyzed Hydrogen-Releasing ortho-Alkenylation of 7-Azaindoles.

Authors :
Li WH
Wu L
Li SS
Liu CF
Zhang GT
Dong L
Source :
Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2016 Dec 12; Vol. 22 (50), pp. 17926-17929. Date of Electronic Publication: 2016 Oct 27.
Publication Year :
2016

Abstract

An efficient rhodium-catalyzed dehydrogenative Heck-type reaction between N-aryl-substituted 7-azaindoles and various alkenes through a H <subscript>2</subscript> -releasing process without the need of any oxidizing agent was developed. The novel methodology broadens the scope of metal-catalyzed hydrogen-releasing reactions to include rhodium catalysis.<br /> (© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.)

Details

Language :
English
ISSN :
1521-3765
Volume :
22
Issue :
50
Database :
MEDLINE
Journal :
Chemistry (Weinheim an der Bergstrasse, Germany)
Publication Type :
Academic Journal
Accession number :
27786383
Full Text :
https://doi.org/10.1002/chem.201603887