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Regioselective Iodine-Catalyzed Construction of Polysubstituted Pyrroles from Allenes and Enamines.

Authors :
Wang Y
Jiang CM
Li HL
He FS
Luo X
Deng WP
Source :
The Journal of organic chemistry [J Org Chem] 2016 Sep 16; Vol. 81 (18), pp. 8653-8. Date of Electronic Publication: 2016 Sep 02.
Publication Year :
2016

Abstract

A novel I2-catalyzed tandem Michael addition/oxidative annulation of allenes and enamines for the construction of polysubstituted pyrroles has been developed. This protocol represents an efficient and highly regioselective way to access functionalized pyrroles in moderate to excellent yields under mild conditions.

Details

Language :
English
ISSN :
1520-6904
Volume :
81
Issue :
18
Database :
MEDLINE
Journal :
The Journal of organic chemistry
Publication Type :
Academic Journal
Accession number :
27559822
Full Text :
https://doi.org/10.1021/acs.joc.6b01737