Back to Search
Start Over
From discrete molecule, to polymer, to MOF: mapping the coordination chemistry of Cd(II) using (113)Cd solid-state NMR.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2016 Aug 23; Vol. 52 (70), pp. 10680-3. - Publication Year :
- 2016
-
Abstract
- Studies of three related Cd(II) systems (a discrete [Cd(II)2] unit, a one-dimensional [Cd(II)2]n coordination polymer and a Cd(II)-based MOF) all derived from the ligand 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine, reveal an exceptionally rare example of (113)Cd-(113)Cd J coupling in the polymer that is detectable by solid-state NMR ((2)JCd-Cd = ∼65 Hz).
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 52
- Issue :
- 70
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 27507123
- Full Text :
- https://doi.org/10.1039/c6cc04940k